First star to use her breasts to arouse

Source: Wikipedia
Not so with Jean Harlow. This latter actress usually gets the credit for focussing the erotic interest, for the first time on the screen, on a woman's breasts. At the end of the nineteen twenties it was the flat-chested flappers who symbolised screen sex. Harlow's breasts were only large (34-inch bust) compared to the boyish females who had appeared on the screen before her- but she heaved up her breasts and used them to advantage.
Harlow was said to be a compulsive exhibitionist, a "sexual provocatrice who knew the effect her body made on men." Her nipples were supposed to expand as the room temperature went up; and before a Press conference she would rub them with ice.